Effect of Glass Fiber Hybridization on the Behavior Under Impact of Woven Carbon Fiber/Epoxy Laminates

The low-velocity impact behavior was studied in hybrid laminates manufactured by RTM with woven carbon and glass (S2) fabrics. Specimens with different thicknesses and glass fiber content (from 0 to 21 vol.%) were tested with impact energies in the range 30–245 J and the resulting deformation and fracture micromechanisms were studied using X-ray microtomography. The results of these analyses, together with those of the impact tests (maximum load and energy absorbed), were used to elucidate the role played by glass fiber hybridization on the fracture micromechanisms and on the overall laminate performance under low-velocity impact

Small-scale mechanical response of cemented carbides: Correlation between mechanical properties and microstructure

The unique combination of hardness, toughness and wear resistance exhibited by heterogeneous hard materials (e.g. cemented carbides, PCD composites, PcBN systems and generic hard coating/substrate combinations) has made them preeminent material choices for extremely demanding applications, such as metal cutting/forming tools or mining bits, where improved and consistent performance together with high reliability are required. The remarkable mechanical properties of these materials results from a two-fold effectiveness associated with their intrinsic composite character. On the one hand in terms of composite nature: combination of completely different phases (hard, brittle and soft, ductile constituents) with optimal interface properties. On the other hand as related to composite assemblage: two interpenetrating-phase networks where toughening is optimized through different mechanisms depending on the relatively different chemical nature among them. In particular, this presentation is focused on WC-Co hardmetals, as reference hard material. Large number of studies has been reported, mainly focused on the mechanical behavior of this composite. On the other hand, information on the small-scale mechanical response of these materials is rather scarce. This is particularly true regarding experimental data and analysis on the influence of phase nature, crystal orientation (anisotropy) and interfacial adhesion strength on hardness, deformation and/or damage mechanisms. It is clear that knowledge of these issues is crucial not only to improve the performance of hardmetals but also to develop ceramic-metal composites beyond WC-Co systems. A systematic micro- and nanomechanical study of the mechanical response of several microstructurally different WC-Co grades is presented. In doing so, nanoindentation technique is implemented and corresponding deformation/damage mechanisms are also investigated. In general, five different approaches are followed to accomplish the main goal of this research: (1) assessment of intrinsic hardness values and main deformation mechanisms as a function of crystal orientation for the carbide phase at room temperature (RT) and also at high temperature (from RT to 600 ºC), (2) determination of effective hardness and flow stress of the metallic binder through massive nanoindentation and statistical analysis, (3) evaluation of the Hall-Petch parameters for the WC-Co as a function of a microstructural parameter (mean free path) by using the methodology presented above, (4) correlation of the microstructure with the hardness and elastic modulus map by using high indentation speed tests, and (5) study of the stress-strain response by means of ex/in-situ compression of micropillars. It is found that WC-Co composites are strongly anisotropic in terms of hardness at the small scale (microstructure), being the WC hardness for the basal plane about 20-30% higher than for the prismatic and pyramidal planes. It implies consideration of carbides with different crystal orientations as distinct phases for statistical analysis of massive nanoindentation data. Implementation of such testing/analysis protocol indicates a flow stress for the constrained Co-based binder of about 2.6-3.5 GPa. By plotting of the experimentally data as a function of the binder mean free path results in a Hall-Petch strengthening relationship. Finally, the compression of micropillars points out that main deformation mechanisms are located in the metallic binder although close to the strong interface exhibited by these materials

Superplastic deformation of directionally solidified nanofibrillar Al2O3-Y3Al5O12-Zr O2 eutectics

Nanofibrillar Al2O3–Y3Al5O12–ZrO2 eutectic rods were manufactured by directional solidification from the melt at high growth rates in an inert atmosphere using the laser-heated floating zone method. Under conditions of cooperative growth, the ternary eutectic presented a homogeneous microstructure, formed by bundles of single-crystal c-oriented Al2O3 and Y3Al5O12 (YAG) whiskers of ˜100 nm in width with smaller Y2O3-doped ZrO2 (YSZ) whiskers between them. Owing to the anisotropic fibrillar microstructure, Al2O3–YAG–YSZ ternary eutectics present high strength and toughness at ambient temperature while they exhibit superplastic behavior at 1600 K and above. Careful examination of the deformed samples by transmission electron microscopy did not show any evidence of dislocation activity and superplastic deformation was attributed to mass-transport by diffusion within the nanometric domains. This combination of high strength and toughness at ambient temperature together with the ability to support large deformations without failure above 1600 K is unique and shows a large potential to develop new structural materials for very high temperature structural applications

Determination of the mechanical properties of amorphous materials through instrumented nanoindentation

A novel methodology based on instrumented indentation is developed to determine the mechanical properties of amorphous materials which present cohesive-frictional behaviour. The approach is based on the concept of a universal hardness equation, which results from the assumption of a characteristic indentation pressure proportional to the hardness. The actual universal hardness equation is obtained from a detailed finite element analysis of the process of sharp indentation for a very wide range of material properties, and the inverse problem (i.e. how to extract the elastic modulus, the compressive yield strength and the friction angle) from instrumented indentation is solved. The applicability and limitations of the novel approach are highlighted. Finally, the model is validated against experimental data in metallic and ceramic glasses as well as polymers, covering a wide range of amorphous materials in terms of elastic modulus, yield strength and friction angle

Microstructure and mechanical properties of physical vapor deposited Cu/W nanoscale multilayers: influence of layer thickness and temperature

Based on our previous knowledge on Cu/Nb nanoscale metallic multilayers (NMMs), Cu/W NMMs show a good potential for applications as heat skins in plasma experiments and armors, and it could be expected that the substitution of Nb by W would increase the strength, particularly at high temperatures. To check this hypothesis, Cu/W NMMs with individual layer thicknesses ranging between 5 and 30 nm were deposited by physical vapor deposition, and their mechanical properties were measured by nanoindentation. The results showed that, contrary to Cu/Nb NMMs, the hardness was independent of the layer thickness and decreased rapidly with temperature, especially above 200 °C. This behavior was attributed to the growth morphology of the W layers as well as the jagged Cu/W interface, both a consequence of the low W adatom mobility during deposition. Therefore, future efforts on the development of Cu/W multilayers should concentrate on optimization of the W deposition parameters via substrate heating and/or ion assisted deposition to increase the W adatom mobility during depositio

Optimum high temperature strength of two-dimensional nanocomposites

High-temperature nanoindentation was used to reveal nano-layer size effects on the hardness of two-dimensional metallic nanocomposites. We report the existence of a critical layer thickness at which strength achieves optimal thermal stability. Transmission electron microscopy and theoretical bicrystal calculations show that this optimum arises due to a transition from thermally activated glidewithin the layers to dislocation transmission across the layers.We demonstrate experimentally that the atomic-scale properties of the interfaces profoundly affect this critical transition. The strong implications are that interfaces can be tuned to achieve an optimum in high temperature strength in layered nanocomposite structures